Photocatalytic degradation of three azo dyes using immobilized Ti02 nanoparticles on glass plates activated by UV light irradiation: Influence of dye molecular structure
Identifieur interne : 000F67 ( Main/Exploration ); précédent : 000F66; suivant : 000F68Photocatalytic degradation of three azo dyes using immobilized Ti02 nanoparticles on glass plates activated by UV light irradiation: Influence of dye molecular structure
Auteurs : A. R. Khataee [Iran, France] ; Marie-Noëlle Pons [France] ; O. Zahraa [France]Source :
- Journal of hazardous materials [ 0304-3894 ] ; 2009.
Descripteurs français
- Pascal (Inist)
- Dégradation photochimique, Colorant azoïque, Nanoparticule, Verre, Rayonnement UV, Structure moléculaire, Structure chimique, Photocatalyse, Industrie textile, Substitut, Oxyde de titane, Catalyseur, Réacteur photochimique, Microscopie électronique balayage, Décoloration, Cinétique, Minéralisation, Surveillance, Carbone organique total, Ammonium, Azote, Ordre 1, Devenir polluant, Particule ultrafine, Epuration physicochimique, Aérosol, Pollution air.
- Wicri :
- topic : Verre, Industrie textile, Azote, Particule ultrafine, Aérosol.
English descriptors
- KwdEn :
- Aerosols, Air pollution, Ammonium, Azo dye, Catalyst, Chemical structure, Discoloration, First order, Glass, Kinetics, Mineralization, Molecular structure, Nanoparticle, Nitrogen, Photocatalysis, Photochemical degradation, Photochemical reactor, Physicochemical purification, Pollutant behavior, Scanning electron microscopy, Substitute, Surveillance, Textile industry, Titanium oxide, Total organic carbon, Ultrafine particle, Ultraviolet radiation.
Abstract
In order to discuss the effect of chemical structure on photocatalysis efficiency, the photocatalytic degradation of three commercial textile dyes (C.I. Acid Orange 10 (AO10), C.I. Acid Orange 12 (AO12) and C.I. Acid Orange 8 (AO8)) with different structure and different substitute groups has been investigated using supported TiO2 photocatalyst under UV light irradiation. All the experiments were performed in a circulation photochemical reactor equipped with a 15-W UV lamp emitted around 365 nm. The investigated photocatalyst was industrial Millennium PC-500 (crystallites mean size 5-10 nm) immobilized on glass plates by a heat attachment method. SEM images of the immobilized TiO2 nanoparticles showed the good coating on the plates, after repeating the deposition procedure three times. Our results indicated that the photocatalytic decolorization kinetics of the dyes were in the order of AO10 > AO12 > AO8. Photocatalytic mineralization of the dyes was monitored by total organic carbon (TOC) decrease, changes in UV-vis spectra and ammonium ion formation. The dye solutions could be completely decolorized and effectively mineralized, with an average overall TOC removal larger than 94% for a photocatalytic reaction time of 6 h. The nitrogen-to-nitrogen double bond of the azo dyes was transformed predominantly into NH4+ ion. The kinetic of photocatalytic decolorization of the dyes was found to follow a first-order rate law. The photocatalysis efficiency was evaluated by figure-of-merit electrical energy per order (EEO).
Affiliations:
- France, Iran
- Grand Est, Lorraine (région)
- Nancy
- Centre national de la recherche scientifique, Laboratoire réactions et génie des procédés, Nancy-Université, Université de Lorraine
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Le document en format XML
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aerosols</term>
<term>Air pollution</term>
<term>Ammonium</term>
<term>Azo dye</term>
<term>Catalyst</term>
<term>Chemical structure</term>
<term>Discoloration</term>
<term>First order</term>
<term>Glass</term>
<term>Kinetics</term>
<term>Mineralization</term>
<term>Molecular structure</term>
<term>Nanoparticle</term>
<term>Nitrogen</term>
<term>Photocatalysis</term>
<term>Photochemical degradation</term>
<term>Photochemical reactor</term>
<term>Physicochemical purification</term>
<term>Pollutant behavior</term>
<term>Scanning electron microscopy</term>
<term>Substitute</term>
<term>Surveillance</term>
<term>Textile industry</term>
<term>Titanium oxide</term>
<term>Total organic carbon</term>
<term>Ultrafine particle</term>
<term>Ultraviolet radiation</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Dégradation photochimique</term>
<term>Colorant azoïque</term>
<term>Nanoparticule</term>
<term>Verre</term>
<term>Rayonnement UV</term>
<term>Structure moléculaire</term>
<term>Structure chimique</term>
<term>Photocatalyse</term>
<term>Industrie textile</term>
<term>Substitut</term>
<term>Oxyde de titane</term>
<term>Catalyseur</term>
<term>Réacteur photochimique</term>
<term>Microscopie électronique balayage</term>
<term>Décoloration</term>
<term>Cinétique</term>
<term>Minéralisation</term>
<term>Surveillance</term>
<term>Carbone organique total</term>
<term>Ammonium</term>
<term>Azote</term>
<term>Ordre 1</term>
<term>Devenir polluant</term>
<term>Particule ultrafine</term>
<term>Epuration physicochimique</term>
<term>Aérosol</term>
<term>Pollution air</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Verre</term>
<term>Industrie textile</term>
<term>Azote</term>
<term>Particule ultrafine</term>
<term>Aérosol</term>
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<front><div type="abstract" xml:lang="en">In order to discuss the effect of chemical structure on photocatalysis efficiency, the photocatalytic degradation of three commercial textile dyes (C.I. Acid Orange 10 (AO10), C.I. Acid Orange 12 (AO12) and C.I. Acid Orange 8 (AO8)) with different structure and different substitute groups has been investigated using supported TiO<sub>2</sub>
photocatalyst under UV light irradiation. All the experiments were performed in a circulation photochemical reactor equipped with a 15-W UV lamp emitted around 365 nm. The investigated photocatalyst was industrial Millennium PC-500 (crystallites mean size 5-10 nm) immobilized on glass plates by a heat attachment method. SEM images of the immobilized TiO<sub>2</sub>
nanoparticles showed the good coating on the plates, after repeating the deposition procedure three times. Our results indicated that the photocatalytic decolorization kinetics of the dyes were in the order of AO10 > AO12 > AO8. Photocatalytic mineralization of the dyes was monitored by total organic carbon (TOC) decrease, changes in UV-vis spectra and ammonium ion formation. The dye solutions could be completely decolorized and effectively mineralized, with an average overall TOC removal larger than 94% for a photocatalytic reaction time of 6 h. The nitrogen-to-nitrogen double bond of the azo dyes was transformed predominantly into NH<sub>4</sub>
<sup>+</sup>
ion. The kinetic of photocatalytic decolorization of the dyes was found to follow a first-order rate law. The photocatalysis efficiency was evaluated by figure-of-merit electrical energy per order (E<sub>EO</sub>
).</div>
</front>
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